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Originally Posted by AntonioLao It's Ok by me, as long as it's falling into a bottomless pit (I don't mean the other connotation of falling into hell but more like free falling without the feeling of gravity). |
Antonio, I am confident you can see my point of view- and either point out where I am wrong, or else see where I am right.
Here is a decent explanation, which you may have read but I encourage you to peruse it again:
http://www.toequest.com/forum/showthread.php?t=1020
Now here is an explanation of the derivation of the partition function:
http://en.wikipedia.org/wiki/Derivation_of_the_partition_function
Read these two things back to back if you please.
Let me highlight a few things from the derivation of the partition function:
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In order to proceed we assume the ergodic hypothesis. This means that we assume that all states corresponding to a given energy are equally probable. (If there are other conserved quantities like particle number, this assumption becomes all states corresponding to a given energy and particle number/charge, and a similar derivation would lead to chemical potentials, electric potentials and the like) For example, vibrational states of a given energy are just as likely to be populated as rotational or electronic states of the same energy.
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In reality, the state vector of the universe actually is not equally probable across the spectrum. However, this is a useful mathematical tool for a first approximation to derive statistical mechanics. Now quantum statistical mechanics allows for probabilities of microstates to be different than unity and the approximation of equally probable states is close enough that it will give us measurable results that conform to statistical laws.. but let us proceed..
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Of these two configurations, the second is much more likely, since any of the N molecules could be in the excited state resulting in a total of N possible arrangements of molecules
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Note- in the derivation they say "since any of the N molecules could be in the excited state"-
all of these microstates are linked into one partition. The probability of the system is given as the sum across these individual probabilities. This is not the same thing as ascertaining the exact probability of a specific microstate.
Why does this matter?
Because it determines our interpretation of reality! And as you have been pointing out- entropy is related to probability.
It is related in the nature of how partitions are divided across microstates. Now I am claiming to you that individual microstates have their own unique, specific, and different probabilities from each other which is different than the "grouped probability" of statistical mechanics.
It is this particular probability which is of interest, and which is "a theory of everything". It is of interest because it describes both on a microscopic and macroscopic level how the universe functions- it functions as a propagation of a wave form from the past into the future- similar to a wave passing through water or air, but where the medium itself is modifying the waveform.